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Become a knowledge manager at UWC 2024
The American Nuclear Society is now accepting applications for knowledge managers to work during the 2024 Utility Working Conference and Vendor Technology Expo. This year’s UWC, “Nuclear Momentum: Advancing Our Clean Energy Future,” will be held August 4–7, 2024, at the JW Marriott Marco Island Beach Resort on Marco Island, Fla.=
Hiroshi Sugai, Kenzo Munakata
Nuclear Technology | Volume 99 | Number 2 | August 1992 | Pages 235-241
Technical Paper | Enrichment and Reprocessing System | doi.org/10.13182/NT92-A34693
Articles are hosted by Taylor and Francis Online.
In solvent extraction for nuclear fuel reprocessing, a stable emulsion called “crud” is formed at the interface between the organic and aqueous phases. Crud is an emulsion stabilized by finely dispersed solids. Process disturbances are often induced by crud. Accordingly, crud should be eliminated from the interface in the extractors. The eliminated crud is stable and highly radioactive; thus, the treatment of this crud may be difficult. Complexes of zirconium and tributyl phosphate (TBP) degradation products, such as phosphoric acid (H3PO4) and mono-n-butyl phosphate (H2MBP), are one source of the fine particles that stabilize emulsions in the extraction process. A chemical treatment method to demulsify crud stabilized by precipitates of Zr-H3PO4 and Zr-H2MBP is studied. Experimental results indicate that neutralization by an alkaline solution, particularly sodium carbonate, is very effective for the destruction of this crud.