This paper presents the results of an experimental/analytical study designed to determine the quantity of hydrogen generated during an accident involving coolant leakage into the plasma chamber of the International Thermonuclear Experimental Reactor (ITER). This hydrogen could represent a potential explosive hazard, provided the proper conditions exist, causing machine damage and release of radioactive material. We measured graphite/steam reaction rates for several graphites and carbon-based composites at temperatures between 1000 and 1700°C. The effects of steam flow rate and partial pressure were also examined. The measured reaction rates correlated well with two Arrhenius type relationships. We used the relationships for GraphNOL N3M in a thermal model to determine that for ITER the quantity of hydrogen produced would range between 5 and 35 kg, depending upon how the graphite tiles are attached to the first wall. While 5 kg is not a significant concern, 35 kg presents an explosive hazard.