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Fusion Science and Technology
Latest News
Glass strategy: Hanford’s enhanced waste glass program
The mission of the Department of Energy’s Office of River Protection (ORP) is to complete the safe cleanup of waste resulting from decades of nuclear weapons development. One of the most technologically challenging responsibilities is the safe disposition of approximately 56 million gallons of radioactive waste historically stored in 177 tanks at the Hanford Site in Washington state.
ORP has a clear incentive to reduce the overall mission duration and cost. One pathway is to develop and deploy innovative technical solutions that can advance baseline flow sheets toward higher efficiency operations while reducing identified risks without compromising safety. Vitrification is the baseline process that will convert both high-level and low-level radioactive waste at Hanford into a stable glass waste form for long-term storage and disposal.
Although vitrification is a mature technology, there are key areas where technology can further reduce operational risks, advance baseline processes to maximize waste throughput, and provide the underpinning to enhance operational flexibility; all steps in reducing mission duration and cost.
P. B. Parks, N. Alexander, C. Moeller, R. Callis
Fusion Science and Technology | Volume 67 | Number 4 | May 2015 | Pages 792-801
Technical Paper | doi.org/10.13182/FST14-834
Articles are hosted by Taylor and Francis Online.
This paper describes two intermediate-scale experiments designed to test basic principles of waveguide pellet acceleration, a novel method of using microwave power to generate propulsive thrust from flash vaporization of a “pusher” medium to accelerate a frozen deuterium-tritium fuel pellet. Results from a low-power stage I experiment using a surrogate pusher consisting of an inert medium with volume-distributed metallic particle absorbers are in good agreement with Parks' wave attenuation theory. In stage II, a high-powered short-pulsed gyrotron source will be used to vaporize a surrogate pusher in a closed system (waveguide/test cell) without an accelerating projectile (pellet) to create a thrust-generating gas of interesting pressures ∼60 to 100 bars and temperatures ∼600 to 1000 K. To compare theory and experiment, the vaporization of various volatile organic compounds with suspended metallic particle absorbers must be examined from a detailed thermodynamic perspective, given that large deviations from ideal-gas behavior arise from the intermolecular forces when these solvents transition from ambient to a dense, warm, supercritical fluid. Using the Peng-Robinson real-gas equation of state, a closed-form expression for the specific internal energy U(V, T) was found that self-consistently includes the intramolecular rotational-vibrational energies, of relevance when measurements of the expanded gas state are taken on timescales faster than the molecular decomposition time. Other thermodynamically significant properties, such as the Joule-Thomson inversion curve, that were calculated from this treatment are in excellent agreement with reported experimental data. This lends further support to the use of surrogate pusher media in place of deuterium.