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Can hydrogen be the transportation fuel in an otherwise nuclear economy?
Let’s face it: The global economy should be powered primarily by nuclear power. And it probably will by the end of this century, with a still-significant assist from renewables and hydro. Once nuclear systems are dominant, the costs come down to where gas is now; and when carbon emissions are reduced to a small portion of their present state, it will become obvious that most other sources are only good in niche settings. I mean, why use small modular reactors to load-follow when they can just produce that power instead of buffering it?
Donald R. Olander, Grant T. Fukuda, C. F. Baes, Jr.
Fusion Science and Technology | Volume 41 | Number 2 | March 2002 | Pages 141-150
Technical Paper | doi.org/10.13182/FST02-A208
Articles are hosted by Taylor and Francis Online.
The pressures of the vapor species in equilibrium with Flibe at ~600°C are determined from work by Buchler and Stauffer and by Baes and coworkers. The former authors show that the principal vapor species are BeF2(g) and LiBeF3(g). The measurements and the theoretical model of Baes provide accurate values of the activity coefficient of BeF2 in Flibe. When combined with the vapor pressure of pure BeF2, the equilibrium pressure of BeF2 is determined as a function of melt composition and temperature. The activity coefficient of LiF is not measured, but it is obtained by application of the Gibbs-Duhem equation to the measured activity coefficient of BeF2. Thus, the partial pressure of LiF(g) is also known. The pressure of the mixed dimer LiBeF3 is calculated from the gas phase equilibrium for the formation of the dimer from the two monomers, with the equilibrium constant given by Buchler and Stauffer. The vapor pressure at 600°C extrapolated from high-temperature Oak Ridge National Laboratory data is ~60% higher than the predicted values.