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Materials Science & Technology
The objectives of MSTD are: promote the advancement of materials science in Nuclear Science Technology; support the multidisciplines which constitute it; encourage research by providing a forum for the presentation, exchange, and documentation of relevant information; promote the interaction and communication among its members; and recognize and reward its members for significant contributions to the field of materials science in nuclear technology.
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Utility Working Conference and Vendor Technology Expo (UWC 2024)
August 4–7, 2024
Marco Island, FL|JW Marriott Marco Island
Standards Program
The Standards Committee is responsible for the development and maintenance of voluntary consensus standards that address the design, analysis, and operation of components, systems, and facilities related to the application of nuclear science and technology. Find out What’s New, check out the Standards Store, or Get Involved today!
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Nuclear Science and Engineering
September 2024
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August 2024
Fusion Science and Technology
Latest News
Taking shape: Fusion energy ecosystems built with public-private partnerships
It’s possible to describe fusion in simple terms: heat and squeeze small atoms to get abundant clean energy. But there’s nothing simple about getting fusion ready for the grid.
Private developers, national lab and university researchers, suppliers, and end users working toward that goal are developing a range of complex technologies to reach fusion temperatures and pressures, confounded by science and technology gaps linked to plasma behavior; materials, diagnostics, and electronics for extreme environments; fuel cycle sustainability; and economics.
Guanghui Wang, Hui He, Yaorui Li, Meng Zhang, Yang Gao, Caishan Jiao
Nuclear Technology | Volume 209 | Number 9 | September 2023 | Pages 1373-1381
Research Article | doi.org/10.1080/00295450.2023.2199905
Articles are hosted by Taylor and Francis Online.
The contaminated solvent from the Purex process is washed with alkaline detergents such as sodium carbonate, which generates a large amount of secondary wastes. Therefore, hydrazine carbonate as a salt-free reagent deserves to be studied in depth. In this study, the Ce(IV), U(VI), and Zr(IV) metal ions in organic phases containing dibutyl phosphate (HDBP) of 30% tributyl phosphate (TBP)–dodecane were washed with hydrazine carbonate. The effects of the oscillation time (1 to 15 min); temperature (25°C to 85°C); cumulative number of washes (one to four times); mass fraction of hydrazine carbonate (0.1% to 20%); volume ratio of the aqueous phase to the organic phase (0.2 to 5); HDBP concentration (0 to 0.4 M); HNO3 concentration (0.05 to 8 M); and concentration of Ce(IV), U(VI), and Zr(IV) metal ions on the removal percentages of Ce(IV), U(VI), and Zr(IV) metal ions in polluted solvents were studied. The results showed that when the organic phase containing 0.02 M HDBP was washed three times with 5% hydrazine carbonate at 25°C, the removal percentages of the Ce(IV), U(VI), and Zr(IV) ions were 96%, 98%, and 94%, respectively. Meanwhile, the retention concentrations of the three in the organic phase were 35, 28, and 78 mg/L, respectively. The increase of the mass fraction of hydrazine carbonate enhances the removal of the metal ions from the organic phase into the aqueous phase. High acid is not conducive to alkaline washing of metal ions. The increase of HDBP concentration not only promotes extraction but also increases the retention capacity of the organic phase and has the most significant effect on Zr(IV). U(VI) promotes the preferential washing of Zr(IV) while Ce(IV) increases the metal retention concentration of Zr(IV) in the organic phase.