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Undeclared uranium hitches a ride on cobalt exports from Congo, study says
Philippe (left) and Manzuk quantified the amount of uranium that has been exported from the DRC in cobalt shipments or left behind in the environment. (Photo: Joel Hallberg/UW–Madison)
Researchers at the University of Wisconsin–Madison and Princeton University have published a study in Nature Communications that calls attention to a blind spot in nuclear nonproliferation: The Democratic Republic of the Congo (DRC) has exported thousands of metric tons of uranium, and there is no accounting for where it has gone.
In partnership with Lighthouse Reports and the Financial Times, UW–Madison nuclear engineering professor and nuclear security expert Sébastien Philippe and Ryan Manzuk, a geologist and research fellow in Philippe’s group and at Princeton, conducted the study using countrywide mineralization and geochemical data.
M. Mirandou, S. Aricó, R. Sanabria, S. Balart, D. Podestá, J. Fabro
Nuclear Technology | Volume 199 | Number 1 | July 2017 | Pages 96-102
Technical Paper | doi.org/10.1080/00295450.2017.1323534
Articles are hosted by Taylor and Francis Online.
Because of their good behavior under irradiation, fuel elements based on U3Si2 particles dispersed in an Al matrix have been used to convert to low-enriched uranium in a large number of research reactors. This behavior is extended to any compound grown by interdiffusion between silicide and Al during the fabrication process.
In this work, two plates fabricated with U3Si2 particles dispersed in an Al matrix were analyzed by optical and scanning electron microscopies, wave length dispersive microanalysis, and X-ray diffraction after the fabrication process. The results show that U(Al,Si)3 together with another phase with the same crystalline structure as U3Si2 but modified cell volume was formed.
A detailed analysis of fuel elements based on U3Si2 is considered very useful to be applied when going into greater depth in the frame of a U(Mo) qualification program.