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June 15–18, 2025
Chicago, IL|Chicago Marriott Downtown
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Smarter waste strategies: Helping deliver on the promise of advanced nuclear
At COP28, held in Dubai in 2023, a clear consensus emerged: Nuclear energy must be a cornerstone of the global clean energy transition. With electricity demand projected to soar as we decarbonize not just power but also industry, transport, and heat, the case for new nuclear is compelling. More than 20 countries committed to tripling global nuclear capacity by 2050. In the United States alone, the Department of Energy forecasts that the country’s current nuclear capacity could more than triple, adding 200 GW of new nuclear to the existing 95 GW by mid-century.
Ned E. Bibler
Nuclear Technology | Volume 34 | Number 3 | August 1977 | Pages 412-415
Technical Paper | Chemical Processing | doi.org/10.13182/NT77-A31805
Articles are hosted by Taylor and Francis Online.
The radiolytic oxidation of Fe(II) and the destruction of sulfamic acid (SA) in feed solutions for solvent extraction purification of 237Np and 238Pu from spent nuclear fuels have been investigated. Cobalt-60 gamma radiolysis of simulated solutions established that 100-eV yields for depletion of Fe(II) and SA are 13 and 5.6, respectively. Also, the normally occurring components of process solutions do not significantly affect these yields. An actual process solution was studied in which radiolysis was almost entirely from gamma-ray and beta-particle decay of 235U fission products along with a small fraction from alpha-particle decay of transuranium isotopes. In this solution, G(Fe3+) is 12, which is in good agreement with results with simulated solutions. Interpretation of the results suggests that Fe(II) not only reduces Np(V) and Pu(IV) but also protects the reduced states from reoxidation by radiolytically formed intermediates; when Fe(II) is depleted, the reduced states are immediately oxidized.