Various sample sizes, reflector sizes and shapes, and reflector materials were examined to determine their effect on pulse-height and pulse-shape resolution in alpha liquid-scintillation spectrometry. A section of a metal sphere coated with a diffuse-white reflective material was found to have the best characteristics for both pulse-height and pulse-shape resolution. Although sample volumes as large as 10 ml could be tolerated when used with reflectors to accommodate them, the best results were obtained with 1-ml samples and smaller reflectors. Comparison of two types of pulse-shape discrimination circuitry for separating alpha and beta-gamma pulses indicated that a zero-crossover method was superior to a constant fraction timing method. The combination of these improved detectors with solvent extraction methods of incorporating the sample in the scintillator and pulse-shape discrimination allows alpha spectrometry with a background as low as 0.01 count/min and an energy resolution as high as 5.5%.