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Undeclared uranium hitches a ride on cobalt exports from Congo, study says
Philippe (left) and Manzuk quantified the amount of uranium that has been exported from the DRC in cobalt shipments or left behind in the environment. (Photo: Joel Hallberg/UW–Madison)
Researchers at the University of Wisconsin–Madison and Princeton University have published a study in Nature Communications that calls attention to a blind spot in nuclear nonproliferation: The Democratic Republic of the Congo (DRC) has exported thousands of metric tons of uranium, and there is no accounting for where it has gone.
In partnership with Lighthouse Reports and the Financial Times, UW–Madison nuclear engineering professor and nuclear security expert Sébastien Philippe and Ryan Manzuk, a geologist and research fellow in Philippe’s group and at Princeton, conducted the study using countrywide mineralization and geochemical data.
Youho Lee, Thomas J. McKrell, Chao Yue, Mujid S. Kazimi
Nuclear Technology | Volume 183 | Number 2 | August 2013 | Pages 210-227
Technical Paper | Fuel Cycle and Management/Materials for Nuclear Systems | doi.org/10.13182/NT12-122
Articles are hosted by Taylor and Francis Online.
An experimental assessment was conducted of the silicon carbide (SiC) cladding oxidation rate in steam under conditions that are representative of loss-of-coolant accidents in light water reactors (LWRs). SiC oxidation tests were performed with monolithic alpha-phase tubular samples at atmospheric pressure for steam temperatures of 1140°C and 1500°C and a Reynolds number range of 40 to 330. Linear weight loss of SiC samples due to boundary layer controlled reaction of silica scale (SiO2 volatilization) was experimentally observed. The weight loss rate increased with increasing steam flow rate and temperature. Over the range of test conditions, SiC oxidation rates were shown to be about three orders of magnitude lower than the oxidation rates of Zircaloy-4. This underlines a weaker interplay between oxidation and mechanical property degradation in comparison with Zircaloy. SiC volatilization correlations for developing laminar flow in a vertical channel were formulated for LWR accident modeling.