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Undeclared uranium hitches a ride on cobalt exports from Congo, study says
Philippe (left) and Manzuk quantified the amount of uranium that has been exported from the DRC in cobalt shipments or left behind in the environment. (Photo: Joel Hallberg/UW–Madison)
Researchers at the University of Wisconsin–Madison and Princeton University have published a study in Nature Communications that calls attention to a blind spot in nuclear nonproliferation: The Democratic Republic of the Congo (DRC) has exported thousands of metric tons of uranium, and there is no accounting for where it has gone.
In partnership with Lighthouse Reports and the Financial Times, UW–Madison nuclear engineering professor and nuclear security expert Sébastien Philippe and Ryan Manzuk, a geologist and research fellow in Philippe’s group and at Princeton, conducted the study using countrywide mineralization and geochemical data.
B. Pollack, B. J. Lewis, D. Kelly
Nuclear Technology | Volume 182 | Number 1 | April 2013 | Pages 39-48
Technical Paper | Fission Reactors/Fuel Cycle and Management | doi.org/10.13182/NT13-A15824
Articles are hosted by Taylor and Francis Online.
Current limitations of Canadian Deuterium Uranium (CANDU) reactors to reliably locate defective fuel bundles have created interest in new identification techniques. Noble gas tagging, which would involve the addition of specific combinations of Kr and Xe isotopes to the fuel-to-sheath gap during manufacturing, has the potential to offer a means of locating failed-fuel bundles on power, where the released tag could be measured in the primary heat transport system by mass spectrometry. Moreover, the technique could be of particular interest for demonstration irradiations with new fuel bundle designs. This work outlines preliminary considerations on the applicability of noble gas tagging for CANDU reactors. This assessment involved the determination of suitable tag isotopes, the simulation of the impact of the tag on the thermal performance of a fuel element, and the determination of the detection limit of a quadrupole inductively coupled plasma-mass spectrometer instrument for krypton samples with typical aqueous concentrations in the range of 10-12 to 10-9 (molKr/molH2O).