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H Canyon restarts uranium recovery operations
The Department of Energy has restarted uranium recovery operations at the Savannah River Site’s H Canyon facility in South Carolina, a move officials say directly supports last year’s executive orders to reinvigorate the nation’s nuclear industrial base and enable the deployment of advanced reactor technologies. The work will include recovering uranium and other scarce isotopes from used nuclear fuel while advancing long-term cleanup goals at the site.
James R. Allensworth, Michael F. Simpson, Man-Sung Yim, Supathorn Phongikaroon
Nuclear Technology | Volume 181 | Number 2 | February 2013 | Pages 337-348
Technical Paper | Reprocessing | doi.org/10.13182/NT13-A15788
Articles are hosted by Taylor and Francis Online.
Methods to improve fission product salt sorption into zeolite-A have been investigated in an effort to reduce waste associated with the electrochemical treatment of spent nuclear fuel. It was demonstrated that individual fission product chloride salts were absorbed by zeolite-A in a solid-state process. As a result, recycling of LiCl-KCl appears feasible via adding a zone-freezing technique to the current treatment process. Ternary salt molten-state experiments showed the limiting kinetics of CsCl and SrCl2 sorption into the zeolite. CsCl sorption occurred rapidly relative to SrCl2 with no observed dependence on zeolite particle size, while SrCl2 sorption was highly dependent on particle size. The application of experimental data to a developed reaction-diffusion-based sorption model yielded diffusivities of 8.04 × 10-6 and 4.04 × 10-7 cm2 /s for CsCl and SrCl2, respectively. Additionally, the chemical reaction term in the developed model was found to be insignificant compared to the diffusion term.