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ORNL–General Atomics partnership on ceramic matrix composites
A memorandum of understanding has been signed by Oak Ridge National Laboratory and General Atomics Electromagnetic Systems (GA-EMS) with the objective of working together on advanced ceramic matrix composite materials for applications in extreme environments. Materials that can withstand extreme temperatures, radiation, corrosion, and mechanical stress are required in aerospace, defense, energy, and other sectors.
According to the agreement, the San Diego–based GA-EMS will use resources from ORNL’s Manufacturing Demonstration Facility to develop “scalable, efficient manufacturing techniques for extreme environment materials including precursors, fibers, composites, and coatings utilized in carbon/carbon (C/C), carbon/silicon carbide (C/SiC), and SiC/SiC composite systems.”
James R. Allensworth, Michael F. Simpson, Man-Sung Yim, Supathorn Phongikaroon
Nuclear Technology | Volume 181 | Number 2 | February 2013 | Pages 337-348
Technical Paper | Reprocessing | doi.org/10.13182/NT13-A15788
Articles are hosted by Taylor and Francis Online.
Methods to improve fission product salt sorption into zeolite-A have been investigated in an effort to reduce waste associated with the electrochemical treatment of spent nuclear fuel. It was demonstrated that individual fission product chloride salts were absorbed by zeolite-A in a solid-state process. As a result, recycling of LiCl-KCl appears feasible via adding a zone-freezing technique to the current treatment process. Ternary salt molten-state experiments showed the limiting kinetics of CsCl and SrCl2 sorption into the zeolite. CsCl sorption occurred rapidly relative to SrCl2 with no observed dependence on zeolite particle size, while SrCl2 sorption was highly dependent on particle size. The application of experimental data to a developed reaction-diffusion-based sorption model yielded diffusivities of 8.04 × 10-6 and 4.04 × 10-7 cm2 /s for CsCl and SrCl2, respectively. Additionally, the chemical reaction term in the developed model was found to be insignificant compared to the diffusion term.