Melting of the nuclear core is one of the severe accident scenarios in a Sodium-cooled Fast Reactor (SFR). During such an event, molten corium may come into contact with the coolant sodium. This interaction of the molten fuel and the coolant is commonly termed molten fuel–coolant interaction (MFCI) in the nuclear industry. In this study, a numerical analysis is carried out to study the solidification of a molten fuel droplet in the liquid sodium pool. In the first part of the study, the effect of constant internal heat generation on the solidification of the droplet is evaluated with convective heat dissipation prescribed at the droplet surface. The internal heat generation (decay power) and the heat transfer coefficient are varied as parameters, and the time required for complete solidification of the molten droplet is obtained. Based on the results, the freezing of the droplet is categorized into three regimes: conduction limited, transition, and internal heat generation dominated regimes. It is observed that the solidification process of nuclear fuel droplets generated during MFCI is not influenced by internal heat generation and lies in a conduction-limited regime for decay power level prevailing in a medium-sized SFR. Hence, in the next part of the study, the numerical analysis is carried out by incorporating the time-dependent decay power and the temperature-dependent heat transfer coefficient in the computational model by developing user-defined subroutines depicting a realistic scenario of an accident. The results of the analysis show that because of the high subcooling of sodium, film boiling is ruled out; nucleate boiling with a maximum heat transfer rate occurs briefly. The heat transfer coefficient then declines as the interface temperature between the droplet and the sodium decreases rapidly until the natural convective regime is reached. A parametric study on the droplet diameter is also carried out by varying the diameter from 0.5 to 10 mm, spanning the typical particle size spectrum expected during MFCI.