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Going Nuclear: Notes from the officially unofficial book tour
I work in the analytical labs at one of Europe’s oldest and largest nuclear sites: Sellafield, in northwestern England. I spend my days at the fume hood front, pipette in one hand and radiation probe in the other (and dosimeter pinned to my chest, of course). Outside the lab, I have a second job: I moonlight as a writer and public speaker. My new popular science book—Going Nuclear: How the Atom Will Save the World—came out last summer, and it feels like my life has been running at full power ever since.
Edgar L. Compere and Jouko E. Savolainen
Nuclear Science and Engineering | Volume 28 | Number 3 | June 1967 | Pages 325-337
Technical Paper | doi.org/10.13182/NSE67-A28946
Articles are hosted by Taylor and Francis Online.
The solubility of hydrogen in liquid alkali metals useful as nuclear reactor coolants varies significantly with pressure and temperature. The solubility of hydrogen in eutectic sodium-potassium mixture (NaK-78) was determined at six temperatures from 300 to 704°C and at pressures below one atmosphere. For unsaturated solutions, the solubility depended on the square root of the hydrogen pressure and varied only slightly with temperature. At temperatures of 300 to 400°C, enough hydrogen could be dissolved at pressures below one atmosphere to result in precipitation of a metal hydride. Precipitation-decomposition pressures were consistent with the literature. The addition to NaK-78 of 1 to 4 at.% lithium considerably diminished the hydrogen activity and resulted in precipitation at lower hydrogen pressure. A mass action model is postulated to explain the phenomena. It is suggested that in liquid-alkali-metal mixtures, dissolved hydrogen exists largely in the form of undissociated metal-hydride molecules or ion pairs, with the different metals combining with the hydrogen in proportion to their concentration and their affinity for hydrogen.