Predicted Water Chemistry in the Primary Coolant Circuit of a Supercritical Water Reactor

Among the six types of Generation IV reactors, the supercritical water reactor (SCWR) is the only one that adopts light water as the reactor coolant. Different from the boiling, two-phase coolant in the core of a traditional boiling water reactor (BWR), the coolant in an SCWR would remain in one phase throughout the entire primary coolant circuit (PCC) due to its much higher operating temperature (>374°C) and pressure (>22.1 MPa). For a conventional BWR, the coolant is relatively oxidizing due to the presence of hydrogen peroxide and oxygen, directly or indirectly produced via water radiolysis. This outcome eventually leads to degradation of structural materials, primarily stress corrosion cracking. In an SCWR, the solubility of oxygen in the reactor coolant is extremely high. In the absence of the gas stripping effect in a single-phase coolant, worse degradation phenomena are expected to appear in the structural and core components. To ensure proper designs of the structural components and suitable selection of the materials to meet the requirements of operation safety, it would be of great assistance to the design engineers of an SCWR to be aware of the intrinsic state of water chemistry in the entire PCC. Since SCWRs are still at the stage of conceptual design and no practical data are available, a computer model was developed for determining the water chemistry variation and the corrosion behavior of metallic materials in the PCC of a conceptual SCWR. Radiolysis parameters used for calculating the concentrations of major redox species (i.e., [O₂], [H₂], and [H₂O₂]) in the reactor coolant were collected from literature reports. However, the lack of sufficient data necessitated that some were derived by extrapolation. Calculations indicated that the concentrations of the two major oxidizing species (H₂O₂ and O₂) could become extremely high at locations inside or near the core, considerably higher than those in typical BWRs. It was therefore speculated that the structural materials in an SCWR may be exposed to an environment not only at a much higher temperature but also one that is more oxidizing than that in a conventional BWR.