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Why should safeguards by design be a global effort?
Jeremy Whitlock
I can’t think of a more exciting time to be working in nuclear, with the diversity of advanced reactor development and increasing global support for nuclear in sustainable energy planning. But we can’t lose sight of the need to plan for efficient international safeguards at the same time.
Global nuclear deployment has been underpinned since 1970 by the Treaty on the Non-Proliferation of Nuclear Weapons (NPT), making it a key customer requirement for governments to demonstrate unequivocally that the technology is not being misused for weapons development.
The International Atomic Energy Agency (IAEA) has helped verify this commitment for more than 50 years, but it has never safeguarded many of the advanced reactors (and related fuel cycle processes) being developed today.
R.-D. Penzhorn, Y. Torikai, S. Naoe, K. Akaishi, A. Perevezentsev, K. Watanabe, M. Matsuyama
Fusion Science and Technology | Volume 57 | Number 3 | April 2010 | Pages 185-195
Technical Paper | doi.org/10.13182/FST57-3-185
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Exposure of Type 316 stainless steel to tritium-containing hydrogen at an elevated temperature causes diffusion of the majority into the bulk and trapping of a small fraction in a thin oxide layer on the surface at concentrations far exceeding those in the bulk. The uptake by the bulk and surface layer is temperature and pressure dependent. After chemical erosion of the tritium-rich layer, the concentration of tritium on the topmost surface is slowly and asymptotically restored even at 298 K. Isothermal heating at 373 or 473 K until substantial release of the bulk tritium is associated with a comparatively much smaller liberation from the surface layer suggesting different retention and liberation mechanisms. The tritium inventory and profile evolution of homogeneously loaded Type 316 stainless steel caused by chronic release at the ambient temperature and radioactive decay were followed experimentally over several years and modeled successfully by a diffusion mechanism. The model has been adapted to specimens nonhomogeneously loaded with tritium only up to the subsurface. It simulates profile and inventory changes well even after prolonged aging. Chronic release constitutes an aging loss of tritium comparable to that of radioactive decay that should be taken into account for the assessment of tritium-contaminated stainless steel waste.