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Smarter waste strategies: Helping deliver on the promise of advanced nuclear
At COP28, held in Dubai in 2023, a clear consensus emerged: Nuclear energy must be a cornerstone of the global clean energy transition. With electricity demand projected to soar as we decarbonize not just power but also industry, transport, and heat, the case for new nuclear is compelling. More than 20 countries committed to tripling global nuclear capacity by 2050. In the United States alone, the Department of Energy forecasts that the country’s current nuclear capacity could more than triple, adding 200 GW of new nuclear to the existing 95 GW by mid-century.
Satoshi Konishi, T. Nagasaki, T. Hayashi, K. Okuno
Fusion Science and Technology | Volume 26 | Number 3 | November 1994 | Pages 668-672
Plasma Fueling and Fuel Cycle | Proceedings of the Eleventh Topical Meeting on the Technology of Fusion Energy New Orleans, Louisiana June 19-23, 1994 | doi.org/10.13182/FST94-A40234
Articles are hosted by Taylor and Francis Online.
Behavior and improvement of the ZrCo based intermetallic materials for tritium recovery, storage and supply are studied. Compound ZrCo was found to be subject to disproportionation at high temperature under high hydrogen pressure to form ZrCo2 and ZrH2. This process is completely reversed by vacuum treatment at temperature above 500°C for several hours. Kinetics of the disproportionation was described to be similar to phase transition that have apparent incuvation time to take place. The logarithmic reaction rate constant was related to the reciprocal temperature. With some precautions drawn from the results, this reaction is not a problem in practice. For the application that needs prolonged supply of relatively high-pressure tritium, solid solution of ZrCo and HfCo was developed as an improvement of the material. Materials otained by arc melting with compoistion of Zr(1−x)HfxCo (0<x<0.5) exhibits single plateaus in pressure - composition isotherms when hydrogenated. Repeated hydrognation - dehydrogenation cycles did not generate separate ZrCo and HfCo phases. The equilibrium hydrogen pressure in the plateau regions are expressed as a functio of reciprocal temperature and increases with increasing HfCo contents. This material provides controlled equilibrium hydrogen pressure required for specific applications of tritium storage nad supply.
