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60 Years of U: Perspectives on resources, demand, and the evolving role of nuclear energy
Recent years have seen growing global interest in nuclear energy and rising confidence in the sector. For the first time since the early 2000s, there is renewed optimism about the industry’s future. This change is driven by several major factors: geopolitical developments that highlight the need for secure energy supplies, a stronger focus on resilient energy systems, national commitments to decarbonization, and rising demand for clean and reliable electricity.
S. Le Tacon, A. Brodier, C. Chicanne, M. Theobald
Fusion Science and Technology | Volume 70 | Number 2 | August-September 2016 | Pages 351-357
Technical Paper | doi.org/10.13182/FST15-240
Articles are hosted by Taylor and Francis Online.
Some experiments implemented on the Laser Megajoule facility (LMJ) require the use of the rare-earth (RE) elements, the lanthanides (57 < Z < 71). Rare-earth metals are known to be unstable under atmospheric conditions and some of them are extremely reactive with air. They may react with oxygen and humidity to form RE oxides. In the present work, we study the oxidation of different RE thin films (gadolinium, dysprosium, and praseodymium) prepared by physical vapor deposition. Energy-dispersion spectroscopy, scanning electron microscopy, Rutherford backscattering spectroscopy, and weight measurement are performed to characterize the corrosion mechanisms as a function of time and aging atmospheres (air, dry box, and vacuum). It appears that the oxidation kinetics depends on atomic number and microstructure of the films. Praseodymium coatings are very quickly corroded (in a few hours) when exposed to air and degrade to a yellow powder. Aluminum layers, used as a diffusion barrier, allow us to preserve praseodymium coatings over a period of several weeks when aging in a dry box. Gadolinium and dysprosium coatings (without a protective layer) are preserved from corrosion due to the formation of a passivation layer on their surface. Whatever Z, a dense microstructure permits us to limit the oxygen content and allows us to stabilize the residual stress.