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Darleane C. Hoffman, transuranium element pioneer, dies at age 98
Hoffman
Nuclear chemist Darleane D. Hoffman, who was renowned for her research on transuranium elements that advanced the understanding of nuclear fission, died on September 4 at her home in Menlo Park, Calif. She was 98.
Iowa origins: Hoffman was born on November 8, 1926, in Terril, Ia. She attended Iowa State University, where she earned a bachelor’s degree in chemistry in 1948 and a doctorate in physical (or nuclear) chemistry in 1951. She then began working as a chemist at Oak Ridge National Laboratory.
Los Alamos research: In 1953, Hoffman began a research position at Los Alamos National Laboratory, where she conducted pioneering work on spontaneous fission. She served as the lab’s first female division leader in charge of the Chemistry and Nuclear Chemistry Division.
R. A. Anderl, R. J. Pawelko, G. R. Smolik, F. Scaffidi-Argentina, D. Davydov
Fusion Science and Technology | Volume 38 | Number 3 | November 2000 | Pages 283-289
Technical Paper | Special Issue on Beryllium Technology for Fusion | doi.org/10.13182/FST00-A36141
Articles are hosted by Taylor and Francis Online.
This paper reports the results of chemical reactivity experiments for Be pebbles (2-mm and 0.2-mm diameter) and Be powder (14–31 μm diameter) exposed to steam at elevated temperatures, 350 to 900°C for pebbles and 400 to 500°C for powders. We measured BET specific surface areas of 0.12 m2/g for 2-mm pebbles, 0.24 m2/g for 0.2-mm pebbles and 0.66 to 1.21 m2/g for Be powder samples. These experiments showed a complex reactivity behavior for the material, dependent primarily on the test temperature. Average H2 generation rates for powder samples, based on measured BET surface areas, were in good agreement with previous measurements for fully-dense CPM-Be. Rates for the Be pebbles, based on measured BET surface areas, were systematically lower than the CPM-Be rates, possibly because of different surface and bulk features for the pebbles, especially surface-layer impurities, that contribute to the measured BET surface area and influence the oxidation process at the material surface.
