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DNFSB spots possible bottleneck in Hanford’s waste vitrification
Workers change out spent 27,000-pound TSCR filter columns and place them on a nearby storage pad during a planned outage in 2023. (Photo: DOE)
While the Department of Energy recently celebrated the beginning of hot commissioning of the Hanford Site’s Waste Treatment and Immobilization Plant (WTP), which has begun immobilizing the site’s radioactive tank waste in glass through vitrification, the Defense Nuclear Facilities Safety Board has reported a possible bottleneck in waste processing. According to the DNFSB, unless current systems run efficiently, the issue could result in the interruption of operations at the WTP’s Low-Activity Waste Facility, where waste vitrification takes place.
During operations, the LAW Facility will process an average of 5,300 gallons of tank waste per day, according to Bechtel, the contractor leading design, construction, and commissioning of the WTP. That waste is piped to the facility after being treated by Hanford’s Tanks Side Cesium Removal (TSCR) system, which filters undissolved solid material and removes cesium from liquid waste.
According to a November 7 activity report by the DNFSB, the TSCR system may not be able to produce waste feed fast enough to keep up with the LAW Facility’s vitrification rate.
H. Christensen, S. Sunder
Nuclear Technology | Volume 131 | Number 1 | July 2000 | Pages 102-123
Technical Paper | Radioactive Waste Management and Disposal | doi.org/10.13182/NT00-A3107
Articles are hosted by Taylor and Francis Online.
Literature data on the effect of water radiolysis products on spent-fuel oxidation and dissolution are reviewed. Effects of gamma radiolysis, alpha radiolysis, and dissolved O2 or H2O2 in unirradiated solutions are discussed separately. Also, the effect of carbonate in gamma-irradiated solutions and radiolysis effects on leaching of spent fuel are reviewed. In addition, a kinetic model for calculating the corrosion rates of UO2 in solutions undergoing radiolysis is discussed. The model gives good agreement between calculated and measured corrosion rates in the case of gamma radiolysis and in unirradiated solutions containing dissolved oxygen or hydrogen peroxide. However, the model fails to predict the results of alpha radiolysis. In a recent study, it was shown that the model gave good agreement with measured corrosion rates of spent fuel exposed in deionized water. The applications of radiolysis studies for geologic disposal of used nuclear fuel are discussed.
