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This division promotes the development and timely introduction of fusion energy as a sustainable energy source with favorable economic, environmental, and safety attributes. The division cooperates with other organizations on common issues of multidisciplinary fusion science and technology, conducts professional meetings, and disseminates technical information in support of these goals. Members focus on the assessment and resolution of critical developmental issues for practical fusion energy applications.
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June 16–19, 2024
Las Vegas, NV|Mandalay Bay Resort and Casino
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Excelsior University student section awarded community education grant
The American Nuclear Society Student Section at Excelsior University in Albany, N.Y., was awarded a $5,000 grant from the ANS Student Section Strategic Fund initiative for its program, Empowering Tomorrow’s Nuclear Innovators: A Collaborative Approach to Nuclear Technology Education and Awareness.
Michael Epstein, Hans K. Fauske, Charles F. Askonas, Marc A. Vial, Patricia Paviet-Hartmann
Nuclear Technology | Volume 163 | Number 2 | August 2008 | Pages 307-320
Technical Paper | Reprocessing | doi.org/10.13182/NT08-A3990
Articles are hosted by Taylor and Francis Online.
A Semenov-type analysis is made of the conditions for an exothermic runaway reaction in an "organic phase" (or "red oil") made up of tri-n-butyl phosphate (TBP) saturated with nitric acid (HNO3). Also, a theoretical framework is developed to predict the critical organic layer depth above which a runaway will occur when the organic layer rests on a layer of aqueous nitric acid ("aqueous phase"). Available calorimetry data on peak pressurization rates during vented TBP/HNO3 reactions are rationalized using orifice flow theory, which provides a simple criterion for the required vent area for vessel pressure relief during a red oil runaway. Finally, it is shown that the Tomsk-7 accident can be explained by a combination of weak reaction tempering at the vessel relief valve set pressure and insufficient venting capacity. The formulations for determining the onset of a TBP/HNO3 runaway outlined in this paper rely heavily on the empirical and semiempirical equations developed in the companion paper "Thermal Stability and Safe Venting of the Tri-N-Butyl Phosphate-Nitric Acid-Water ("Red Oil") System - II: Experimental Data on Reaction Self-Heat Rates and Gas Production and Their Correlation," Nuclear Technology, Vol. 163, p. 294 (2008), which deals with the chemical self-heat rate in the organic phase, the gas production rate in the organic phase, and the superficial gas velocity across the aqueous-organic interface of a two-layer organic over aqueous configuration.