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Undeclared uranium hitches a ride on cobalt exports from Congo, study says
Philippe (left) and Manzuk quantified the amount of uranium that has been exported from the DRC in cobalt shipments or left behind in the environment. (Photo: Joel Hallberg/UW–Madison)
Researchers at the University of Wisconsin–Madison and Princeton University have published a study in Nature Communications that calls attention to a blind spot in nuclear nonproliferation: The Democratic Republic of the Congo (DRC) has exported thousands of metric tons of uranium, and there is no accounting for where it has gone.
In partnership with Lighthouse Reports and the Financial Times, UW–Madison nuclear engineering professor and nuclear security expert Sébastien Philippe and Ryan Manzuk, a geologist and research fellow in Philippe’s group and at Princeton, conducted the study using countrywide mineralization and geochemical data.
Paul K. Chan, Stephane Paquette, Hugues W. Bonin
Nuclear Technology | Volume 191 | Number 1 | July 2015 | Pages 1-14
Technical Paper | Fuel Cycle and Management | doi.org/10.13182/NT14-67
Articles are hosted by Taylor and Francis Online.
A CANDU lattice cell has been modeled using the Los Alamos National Laboratory's MCNP 6 code and Atomic Energy of Canada Limited's WIMS-AECL 3.1. Models for the CANDU 37-element fuel bundle have included a CANLUB coating, as a carrier for the neutron absorbers. The objective is to improve CANDU reactor operating margins by adding small amounts (∼1 g) of neutron absorbers to each fuel element.
For CANDU natural uranium fuel bundle design, the results indicate that (a) the fueling transient (due to the xenon-free effect) could be significantly reduced using gadolinium oxide (Gd2O3), with no significant impact on fuel burnup, and (b) the reactivity peak (due to plutonium production) could be reduced using europium oxide (Eu2O3), with minimal impact on fuel burnup. An appropriate mixture of Gd2O3 and Eu2O3 that will improve operation and safety margins while having a minimal impact on fuel burnup is determined.
Reactivity and power calculations for various mixtures of Gd2O3 and Eu2O3 are reported here. It is concluded that ∼180 mg Gd2O3 and ∼1000 mg Eu2O3 (∼4.9 ×10−3 wt% per bundle) are sufficient to suppress the refueling transient and lower the axial plutonium peak, with a 0.27% burnup penalty (which is a small impact).
Fuel safety and performance are always important topics for a nuclear utility. This approach of a relatively simple application of burnable poisons to existing CANDU natural uranium fuel design offers the benefits of improving fuel utilization and safety margins.