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INL reports findings on unusual quantum behavior of plutonium
Scientists at Idaho National Laboratory have discovered that plutonium hexaboride (PuB6) displays a type of unusual quantum property called a topological Kondo insulating state. Materials with this property are neither typical electricity conductors nor regular insulators. Rather, they have exterior surfaces that strongly conduct electricity and interiors that block electricity.
Leonardo Romero, Luis Moreno, Ivars Neretnieks
Nuclear Technology | Volume 110 | Number 2 | May 1995 | Pages 238-249
Technical Paper | Radioactive Waste Management | doi.org/10.13182/NT95-A35121
Articles are hosted by Taylor and Francis Online.
The evolution and formation of a redox front in the near field of a repository for high-level nuclear waste is modeled, considering the effect of a time-dependent source term of the oxidizing species produced by radiolysis of the water entering the canister. The transport of oxidants in the clay surrounding the canister occurs by diffusion. In the rock, the transport of oxidants is modeled as occurring through fractures, with diffusion into the rock matrix. The results show that it is not probable that the redox front will ever move past the bentonite. If it does, the tips of the redox front may move <100 m over a million year period in a channel with a high flow rate.