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INL reports findings on unusual quantum behavior of plutonium
Scientists at Idaho National Laboratory have discovered that plutonium hexaboride (PuB6) displays a type of unusual quantum property called a topological Kondo insulating state. Materials with this property are neither typical electricity conductors nor regular insulators. Rather, they have exterior surfaces that strongly conduct electricity and interiors that block electricity.
Wim J. Soppe, Jan Prij
Nuclear Technology | Volume 107 | Number 3 | September 1994 | Pages 243-253
Technical Paper | Radioactive Waste Management | doi.org/10.13182/NT94-A35005
Articles are hosted by Taylor and Francis Online.
In many countries rock salt formations are candidates to host nuclear waste repositories. One of the aspects that needs careful consideration before such a repository can be put into operation is the formation of radiation damage in the salt. A model has been developed that provides a fundamental understanding of the buildup of radiation damage in NaCl. This model is based on kinetic rate reactions and takes into account the effect of impurities and the colloid nucleation stage on the growth of metallic sodium colloids. With this model, we have calculated the amounts of NaCl that can be converted into metallic sodium and molecular Cl2 for various options for repository design and intermediate storage times. It is shown that the concentrations of these defect aggregates, even very close to the high-level radioactive waste containers with steel walls 5 mm-thick, will be limited to a few mole percent.