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INL reports findings on unusual quantum behavior of plutonium
Scientists at Idaho National Laboratory have discovered that plutonium hexaboride (PuB6) displays a type of unusual quantum property called a topological Kondo insulating state. Materials with this property are neither typical electricity conductors nor regular insulators. Rather, they have exterior surfaces that strongly conduct electricity and interiors that block electricity.
Chaitanyamoy Ganguly, Parameshwar Venkappa Hegde, Gyan Chand Jain
Nuclear Technology | Volume 105 | Number 3 | March 1994 | Pages 346-354
Technical Paper | Nuclear Fuel Cycle | doi.org/10.13182/NT94-A34935
Articles are hosted by Taylor and Francis Online.
Around 200 kg of (Pu0.55 U0.45)C fuel pellets of relatively low density (86 ± 2% theoretical density) would be used as a driver fuel in the second core of the Fast Breeder Test Reactor in India. The current paper summarizes the production experience of the initial 15 kg of these fuel pellets following the “vacuum carbothermic synthesis” of tableted oxide-graphite powder mixture followed by “cold-pelletization” of carbide powder and “sintering.” The alterations made in the process equipment, radiation shielding arrangements, and fabrication parameters have been highlighted. The carbothermic synthesis and sintering were carried out in batches of 600 g and 1 kg, respectively. The percentage recovery of sintered pellets in all the batches was >90%. The resintering tests of pellets showed only marginal change in sintered density, ensuring minimum in-pile densification.