In Situ Chlorine Generation and Rare Earth Chlorination by Molten Salt Electrolysis

Chloride volatility processes for purifying actinide and rare earth elements have historically required the use of Cl₂ tanks. To minimize the hazards associated with these processes, an apparatus was designed to produce Cl₂ via molten salt electrolysis. Within this apparatus, one can generate Cl₂, chlorinate metals, and consume excess Cl₂. Here, electrode materials were tested for their ability to generate Cl₂, the composition of the gaseous electrolysis product was evaluated using a quadrupole mass spectrometer, and a Ce foil sample was successfully chlorinated using the electrochemically generated Cl₂.