ANS is committed to advancing, fostering, and promoting the development and application of nuclear sciences and technologies to benefit society.
Explore the many uses for nuclear science and its impact on energy, the environment, healthcare, food, and more.
Division Spotlight
Robotics & Remote Systems
The Mission of the Robotics and Remote Systems Division is to promote the development and application of immersive simulation, robotics, and remote systems for hazardous environments for the purpose of reducing hazardous exposure to individuals, reducing environmental hazards and reducing the cost of performing work.
Meeting Spotlight
2024 ANS Annual Conference
June 16–19, 2024
Las Vegas, NV|Mandalay Bay Resort and Casino
Standards Program
The Standards Committee is responsible for the development and maintenance of voluntary consensus standards that address the design, analysis, and operation of components, systems, and facilities related to the application of nuclear science and technology. Find out What’s New, check out the Standards Store, or Get Involved today!
Latest Magazine Issues
May 2024
Jan 2024
Latest Journal Issues
Nuclear Science and Engineering
June 2024
Nuclear Technology
Fusion Science and Technology
Latest News
Excelsior University student section awarded community education grant
The American Nuclear Society Student Section at Excelsior University in Albany, N.Y., was awarded a $5,000 grant from the ANS Student Section Strategic Fund initiative for its program, Empowering Tomorrow’s Nuclear Innovators: A Collaborative Approach to Nuclear Technology Education and Awareness.
Michael Epstein, Hans K. Fauske, Charles F. Askonas, Marc A. Vial, Patricia Paviet-Hartmann
Nuclear Technology | Volume 163 | Number 2 | August 2008 | Pages 294-306
Technical Paper | Reprocessing | doi.org/10.13182/NT08-A3989
Articles are hosted by Taylor and Francis Online.
Adiabatic calorimetry testing was performed to determine the Arrhenius relations for the chemical self-heat rates generated by the oxidation of tri-n-butyl phosphate saturated with nitric acid ("organic phase"). The adiabatic calorimetry tests showed that the runaway reaction is tempered at ~109°C when the organic phase rests on top of a layer of aqueous nitric acid ("aqueous phase"). It is believed that tempering in the laboratory-scale two-layer organic/aqueous system is mainly due to the upward transport of dissolved water from the aqueous phase to the organic phase where the water evaporates into rising reaction product gas bubbles. The rate of water transport depends strongly on the location and rate of product gas bubble generation. Isothermal tests were performed that clearly reveal that the reaction product gas bubbles originate in the underlying aqueous layer and that their rate of generation is bubbling enhanced reactant mass transfer controlled. A semiempirical expression for the rate of gas generation was developed from the measurements and from available correlations on enhanced mass transfer in bubbling pools. The empirical and semiempirical relations reported here for chemical self-heat rates and reaction product gas production are necessary to determine the thermal stability boundaries of single-layer and two-layer systems, predictions of which appear in the companion paper, "Thermal Stability and Safe Venting of the Tri-N-Butyl Phosphate-Nitric Acid-Water ("Red Oil") System - III: Predictions of Thermal Stability Boundaries and Required Vent Size," Nuclear Technology, Vol. 163, p. 307 (2008).