The cumulative and independent yields of various fission products within the mass ranges of 83 to 117 and 123 to 161 have been measured in the epi-cadmium neutron-induced fission of 245Cm by using an off-line gamma-ray spectrometric technique. Charge distribution correction was applied on the cumulative yields to obtain the post-neutron mass yield distribution. From the mass yield distribution data, the full-width at tenth-maximum of light and heavy mass wings, average light mass <AL> and heavy mass <AH>, average neutron number <ν>, and peak-to-valley ratio were obtained for the first time. Comparison of mass yield distributions was made between the epi-cadmium and thermal neutron–induced fission of 245Cm to examine the role of excitation energy on the nuclear structure effect and P/V ratio.