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Front-end nuclear fuel supply cooperation: Turning allied interdependence into strategic advantage
The global nuclear revival, which is fueled by unprecedented demand for firm, affordable, dispatchable power for artificial intelligence and data center build-out, energy security imperatives, and climate commitments, has exposed a structural reality of the Western fuel cycle: No single allied nation currently possesses the full suite of front-end capabilities. From mining through conversion, enrichment, fabrication, and the emerging deconversion and metallization steps required for reactor fuels, capability is distributed across Canada, France, Japan, the United Kingdom, and the United States (collectively, the “Sapporo Five”), as well as a small group of close partners.
Edgar L. Compere and Jouko E. Savolainen
Nuclear Science and Engineering | Volume 28 | Number 3 | June 1967 | Pages 325-337
Technical Paper | doi.org/10.13182/NSE67-A28946
Articles are hosted by Taylor and Francis Online.
The solubility of hydrogen in liquid alkali metals useful as nuclear reactor coolants varies significantly with pressure and temperature. The solubility of hydrogen in eutectic sodium-potassium mixture (NaK-78) was determined at six temperatures from 300 to 704°C and at pressures below one atmosphere. For unsaturated solutions, the solubility depended on the square root of the hydrogen pressure and varied only slightly with temperature. At temperatures of 300 to 400°C, enough hydrogen could be dissolved at pressures below one atmosphere to result in precipitation of a metal hydride. Precipitation-decomposition pressures were consistent with the literature. The addition to NaK-78 of 1 to 4 at.% lithium considerably diminished the hydrogen activity and resulted in precipitation at lower hydrogen pressure. A mass action model is postulated to explain the phenomena. It is suggested that in liquid-alkali-metal mixtures, dissolved hydrogen exists largely in the form of undissociated metal-hydride molecules or ion pairs, with the different metals combining with the hydrogen in proportion to their concentration and their affinity for hydrogen.