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Front-end nuclear fuel supply cooperation: Turning allied interdependence into strategic advantage
The global nuclear revival, which is fueled by unprecedented demand for firm, affordable, dispatchable power for artificial intelligence and data center build-out, energy security imperatives, and climate commitments, has exposed a structural reality of the Western fuel cycle: No single allied nation currently possesses the full suite of front-end capabilities. From mining through conversion, enrichment, fabrication, and the emerging deconversion and metallization steps required for reactor fuels, capability is distributed across Canada, France, Japan, the United Kingdom, and the United States (collectively, the “Sapporo Five”), as well as a small group of close partners.
Kostadin Dinov, Chihiro Matsuura, Daisuke Hiroishi, Kenkichi Ishigure
Nuclear Science and Engineering | Volume 113 | Number 3 | March 1993 | Pages 207-216
Technical Paper | doi.org/10.13182/NSE92-36
Articles are hosted by Taylor and Francis Online.
The solubility of NiO and CoO in high-temperature water is measured at temperatures between 373 and 523 K in a special batch autoclave system. Great importance has been given to deriving reliable thermodynamical data for the related ionic species at elevated temperatures. The experimental results for NiO seem to be consistent with the previously proposed free-energy data set for Ni2+. Because of the lack of experimental information on the free energy of formation (ΔG°f) for Co2+, the Criss-Cobble approach is used to calculate the values. The estimates are compared with the experimental results. It is concluded that the application of the Criss-Cobble procedure to Co2+ ions is not correct above 423 K. Based on the experiments, a new set of ΔG°f values for Co2+ is proposed.