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College students help develop waste-measuring device at Hanford
A partnership between Washington River Protection Solutions (WRPS) and Washington State University has resulted in the development of a device to measure radioactive and chemical tank waste at the Hanford Site. WRPS is the contractor at Hanford for the Department of Energy’s Office of Environmental Management.
H. T. Bach, R. B. Schwarz, D. G. Tuggle
Fusion Science and Technology | Volume 48 | Number 1 | July-August 2005 | Pages 545-550
Technical Paper | Tritium Science and Technology - Materials Interaction and Permeation | doi.org/10.13182/FST05-A984
Articles are hosted by Taylor and Francis Online.
We have used resonant ultrasound spectroscopy to measure the three independent elastic constants of Pd-H, Pd-D, and Pd-T single crystal at 300K as a function of hydrogen, deuterium, and tritium concentration, respectively. The addition of interstitial H (D, or T) atoms, located at (0,½,0) in the fcc Pd lattice, affects all three elastic constants C', C44, and B. In the mixed (+) phase, and with increasing H isotope, the shear modulus C' shows an abnormal softening whereas C44 and B do not. This is explained in terms of Zener-type an elastic relaxations affecting the shape of the hydride phases in the coherent(+) two-phase mixture In the single -phase, C' shows a strong isotope dependence whereas C44 and B show none. This behavior is explained in terms of differences in the excitation of optical phonons. In Pd-T, 3He is produced by the radioactive decay of tritium. We have measured in situ the swelling and the change in the elastic constants in Pd-T as a function of aging time. Aging (3He formation) affects all three elastic constants. These measurements are being used to understand the early stages of 3H-3He cluster formation in aged Pd-T crystal.