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WIPP: Lessons in transportation safety
As part of a future consent-based approach by the federal government to site new deep geologic repositories for nuclear waste, local communities and states that are considering hosting such facilities are sure to have many questions. Currently, the Waste Isolation Pilot Plant in New Mexico is the only example of such a repository in operation, and it offers the opportunity for state and local officials to visit and judge for themselves the risks and benefits of hosting a similar facility. But its history can also provide lessons for these officials, particularly the political process leading up to the opening of WIPP, the safety of WIPP operations and transportation of waste from generator facilities to the site, and the economic impacts the project has had on the local area of Carlsbad, as well as the rest of the state of New Mexico.
Weidong Ding, Hongguang Yang, Qin Zhan
Fusion Science and Technology | Volume 80 | Number 2 | February 2024 | Pages 205-214
Research Article | doi.org/10.1080/15361055.2023.2216533
Articles are hosted by Taylor and Francis Online.
The ZrCo-based alloy is considered one of the most promising materials for hydrogen isotope storage in the conceptual design of a fusion reactor. However, there are few systematic studies on the thermodynamic and kinetic models of hydrogen absorption in the new Zr0.8Ti0.2Co alloy. The aim of this study is to computationally derive the general mathematical equations for the thermodynamics and kinetics of hydrogen absorption by Zr0.8Ti0.2Co. In order to obtain the thermodynamic and kinetic data quickly, a constant-flow hydrogen absorption test was used in this study. The thermodynamic performance test revealed that the Zr0.8Ti0.2Co hydrogen absorption transition process was switched from ZrCo to ZrCoHx (metastable phase) and then to ZrCoH3 with an enthalpy of hydrogenation (ΔH) of 66.59 kJ·mol−1 H2, which was obviously lower than that of the ZrCo-based alloy due to the metastable phase.
A mathematical model of the hydrogen absorption coupled with the kinetic equations was established by kinetic process analysis. The hydrogen absorption process was divided into two stages, and the Johnson-Mehl-Avrami-Kolmogorov (JMAK) model could fit the two stages of the Zr0.8Ti0.2Co hydrogen absorption well. In the first stage, the JMAK index was n1 = 1.04, activation energy Ea1 = 7594.6 J/mol, and rate coefficient of reaction k01 = 1.958E-4 s−1. While in the second stage, it was n2 = 1.39, Ea2 = 5221 J/mol, and k02 = 9.938E-5 s−1. Based on the range of n values, it can be inferred that both the nucleation and growth mechanisms or the diffusion mechanism were expressed as the rate-limiting steps. Combined with the simulation software, metal hydride bed performance could be better investigated and the structural design could be guided by the obtained mathematical equation of Zr0.8Ti0.2Co hydriding.
