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Fusion Science and Technology
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Latest News
The legacy of Windscale Pile No. 1
The core of Pile No. 1 at Windscale caught fire in the fall of 1957. The incident, rated a level 5, “Accident with Wider Consequences,” by the International Nuclear and Radiological Event Scale (INES), has since inspired nuclear safety culture, risk assessment, accident modeling, and emergency preparedness. Windscale also helped show how important communication and transparency are to gaining trust and public support.
C. Postolache, Lidia Matei, Gh. Ionita
Fusion Science and Technology | Volume 48 | Number 1 | July-August 2005 | Pages 688-691
Technical Paper | Tritium Science and Technology - Properties, Reactions, and Applications | doi.org/10.13182/FST05-A1017
Articles are hosted by Taylor and Francis Online.
The behavior of hydrophobic catalyst in the isotopic exchange reactions H/D/T was analyzing by quantum chemical methods.The primary radiolytic effect was evaluated using a two-step radiolytic mechanism: a) the ionization of molecule and spatial redistribution of atoms in order to reach a minimum value of energy, characteristic to the new quantum state; b) the neutralization of molecule by capture of an electron and its rapid dissociation in free radicals. Chemical bonds suspected to break are located in the distribution region of LUMO orbital and have minimal bond energy.Evaluation of secondary effects taking place in polymeric structure in the presence of water was carried out through the study of the transition state resulted after the attack of HO radicals formed in the radiolysis of tritiated water.
