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Home / Store / Journals / Electronic Articles / Fusion Science and Technology / Volume 45 / Number 2

Aromatic Polyimides with High Performances and Deuteration

E. Anselmi, J. Raby, A. Balland-Longeau

Fusion Science and Technology / Volume 45 / Number 2 / Pages 157-164

March 2004

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Inertial Confinement Fusion experiments are conducted in polymer capsule in which nuclear products are located. In order to vary optical properties, we need to develop polyimides with high mechanical properties in which we have to substitute all the hydrogen atoms by deuterium atoms. The best way to obtain deuterated polymer is to deuterate monomers instead of direct deuteration of polymers. In a first part, mechanical properties of aromatic polyimide films based on two dianhydrides (pyromellitic dianhydride PMDA and 3,3',4,4'-biphenyltetracarboxylic dianhydride BPDA) and two diamines (4,4'-oxydianiline ODA and pphenylenediamine PDA) have been described. The optimization of synthesis and fabrication parameters of polyimide films PMDA/ODA and BPDA/PDA having high inherent viscosity, so high molecular weight, have allowed us to obtain high mechanical properties. And in a second part, deuterated monomers have been synthesized via multi-steps organic reactions and/or under pressure conditions. We have investigated the preparation of deuterated poly(amic-acid) solutions in NMP and the preparation of the corresponding polyimides deuterated membranes. Results show that deuterium does not affect the reactivity of monomers to form the poly(amic-acid) solution.

 
 
 
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