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Fusion Science and Technology
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Glass strategy: Hanford’s enhanced waste glass program
The mission of the Department of Energy’s Office of River Protection (ORP) is to complete the safe cleanup of waste resulting from decades of nuclear weapons development. One of the most technologically challenging responsibilities is the safe disposition of approximately 56 million gallons of radioactive waste historically stored in 177 tanks at the Hanford Site in Washington state.
ORP has a clear incentive to reduce the overall mission duration and cost. One pathway is to develop and deploy innovative technical solutions that can advance baseline flow sheets toward higher efficiency operations while reducing identified risks without compromising safety. Vitrification is the baseline process that will convert both high-level and low-level radioactive waste at Hanford into a stable glass waste form for long-term storage and disposal.
Although vitrification is a mature technology, there are key areas where technology can further reduce operational risks, advance baseline processes to maximize waste throughput, and provide the underpinning to enhance operational flexibility; all steps in reducing mission duration and cost.
K. J. Heroux, G. A. Morgan
Fusion Science and Technology | Volume 67 | Number 2 | March 2015 | Pages 375-378
Proceedings of TRITIUM 2013 | doi.org/10.13182/FST14-T32
Articles are hosted by Taylor and Francis Online.
The Thermal Enhancement Cartridge Heater Modified (TECH Mod) tritium hydride bed is an interim replacement for the 1st generation (Gen 1) process hydride beds currently in service in the Savannah River Site (SRS) Tritium Facilities. Three new features are implemented in the TECH Mod hydride bed prototype: internal electric cartridge heaters, porous divider plates, and copper foam discs. These modifications will enhance bed performance and reduce costs by improving bed activation and installation processes, in-bed accountability measurements, end-of-life bed removal, and He-3 recovery. A full-scale hydride bed test station was constructed at the Savannah River National Laboratory (SRNL) in order to evaluate the performance of the prototype TECH Mod hyd ride bed. Controlled hydrogen (H2) absorption/desorption experiments were conducted to validate that the conceptual design changes have no adverse effects on the gas transfer kinetics or H2 storage/release properties compared to those of the Gen 1 bed. Inert gas expansions before, during, and after H2 flow tests were used to monitor changes in gas transfer rates with repeated hydriding/dehydriding of the hydride material. The gas flow rates significantly decreased after initial hydriding of the material; however, minimal changes were observed after repeated cycling. The data presented herein confirm that the TECH Mod hydride bed would be a suitable replacement for the Gen 1 bed with the added enhancements expected from the advanced design features.